
Mohawk College - Introduction to Metal Casting
...
MATL MTB72 Module 1 - Course Notes...
Whutz-Up
with Sand?
Since Molten Metal
is hot, and the utility of the mold is the space that it does not consume, the
mold material has to withstand the heat of the metal without melting, losing
it's shape, size etc... Since Sand Molding is done with Sand, the sand must not
melt and it's physical dimensioning should remain intact.
Since sand is
generally a ceramic based material it typically has a strong inter atomic
bonding structure that contributes to it's ability to withstand high
temperatures before breaking down.
Since High
Temperature is a subjective term, lets generalize that most sands have a melting
point above 3000F.
The popularity of
sand as a molding material is due to it's abundance and relatively inexpensive
cost.
"Daddy,
where does sand come from?"
I'm glad you
asked... Sand has many sources and compositions, but all sands have their common
origin in the fact that they are granular material resulting from the disintegration
or crushing of rock.
Of the various
bodies that influence and advise the metal casting industry the AFS (American
Foundry Society) will provide the standards, terms and ranges of measurement
used in this course.
The AFS states
that sand is "Mineral Material" regardless of chemical composition,
and casting sand falls into a broad range of grain sizes that span 2mm to
0.05mm. 1/12" to 1/500" or #10 to #200 Mesh screening.
The four basic
sand compositions discussed in this course are Silica, Olivine, Ziron and
Chromite. These types of sand have various properties that effect their
application to the broad spectrum of foundry work.
Of the numerous
properties the most important are Shape, Melting point, Thermal Expansion,
Weight (measured by Bulk Density and Specific Gravity) and pH. The Chemical
composition of these sands provides some insight into why the other properties
are attributed to the various types.
The following
charts are based on AFS data listed in AFS pub "Technology of Metal
Casting" ISBN #0-87433-257-5.
Sand Chemistry
& Property Table
Composition %
|
Silica
|
Olivine
|
Chromite
|
Ziron
|
SiO2
|
98.82
|
41.2
|
1.34
|
33.5
|
MgO
|
0.031
|
49.4
|
8.75
|
-
|
Cr2O3
|
-
|
-
|
45.8
|
-
|
ZrO2
|
-
|
-
|
-
|
65
|
Al2O3
|
0.049
|
1.8
|
21.34
|
1
|
Fe2O3
|
0.019
|
7.1
|
19.50
|
0.03
|
CaO
|
0.0016
|
0.2
|
0.94
|
-
|
TiO2
|
0.012
|
-
|
0.03
|
0.19
|
Melting Point F(C)
|
3110(1710)
|
3400(1875)
|
3800(2093)
|
4600(2538)
|
Properties
|
Silica
|
Olivine
|
Chromite
|
Ziron
|
Colour
|
White/Brown
|
Green
|
Black
|
White
|
Specific Gravity
|
2.65-2.67
|
3.27-3.37
|
4.3-4.5
|
4.6-4.7
|
Bulk Density
|
95-97
|
96-103
|
156-165
|
152-183
|
Thermal Expansion
|
0.018
|
0.0083
|
0.0045
|
0.0037
|
Temp Reaction (pH)
|
Acidic
|
Basic
|
Basic/Neutral
|
Slightly Acidic
|
Shape
|
Varied
|
Angular
|
Angular
|
Rounded
|
This chart is
important, why the fuck do you think I re-typed it (it's in the text, it's in
the lecture, it's a slide, it's even referred to in the audio files and I think
references are made to it in the video clips)... I believe that like the
infinite constant Pi all answers to this module are contained within the chart
above...
Sand Type Verbiage
Silica
Silica is the most
common sand type and can be found where ever water has had the time to erode
rock to a granular form over time. Lakes, rivers, river banks etc.
In North America
Pure Silica Sand is mined primarily in the Illinois and Missouri States from the
St. Peter deposit, all other silica deposits tend to have varying degrees of
organic and mineral contaminants that must be removed prior to classification as
Casting Sand. These organic and mineral contaminants effect castings in numerous
ways including but not limited to introduction of carbon into the cast,
unpredictable thermal expansion and binding properties to name a few.
Key Info;
High
thermal Expansion 0.018"/inch, Melting point 3110F/1710C, a varied shape
and acidic pH.
Olivine
Olivine Sand is an
ortho-silicate of Magnesium (Mg) and Iron (Fe) and is found in it's natural
state within Forsterite Mg2SiO4
and Fayalite Fe2SiO4(neither
terms are overly relevant to this course) Except that Cast quality Olivine is
only derived form 90% Forsterite...
The Forsterite is
crushed to reduce the mineral to a granular form, logically increasing the cost
due to production of the material.
Olivine sand is
typically used in the Non-Ferrous foundry sector, but is used occasionally in
the Ferrous Sector to aid in the production of Manganese (Mn) Steel (Austentic)
due to it's ability to overcome adverse chemical reactions that would result if
Silica sand were used.
Key Info;
Low
thermal Expansion 0.0083"/inch, Melting point 3400F/1875C, an angular shape
and basic pH.
Chromite FeCr2O4
This is an African
Sand, as it comes from Africa, and has a price tag to reflect its point of
origin.
There is so much I
could say about Chromite FeCr2O4,
but won't as it's not germane to this discussion, but I will note that it is
used in Steel foundries, and as a facing or core material where it's superior
thermal characteristics are called upon...
Key Info;
Low
thermal Expansion 0.004"/inch, Melting point 3800F/2093C, an angular shape
and basic/neutral pH.
Zircon
This is the last
of the four sand types and has the fanciest name... Zirconium Silicate or ZrSio4
to his friends is found primarily in Australia, Florida and California. With the
most stable thermal properties of the 4 types it is used as a mold or mold
facing material where very high temperatures are encountered and refractoriness
becomes a consideration.
Oh and before I
forget, that High refractoriness can aid in "Directional
Solidification" if your a keener and can figure that stuff out when you
make your mold.
And another minor
point that might be worth knowing Zircon has trace elements of Uranium and
Thorium , no big deal... Just so you know... Dispose of as the law tells you,
though it doesn't say specifically that the sand itself is hazardous...
Key Info;
Lowest
thermal Expansion 0.003"/inch, Melting point 4600F/2538C, an elliptical or
rounded shape and slightly acidic pH, an AFS gfn of 65 to 140 with 100 as the
most common.
So why all
the hype on Thermal Expansion???
Although Silica
Sand is the most common sand, it has some characteristics that influence it's behavior
when used within a mold.
The silica is
considered to be in an Alpha Quartz State when below approx 2000F, above
that temp it changes to a Beta Quartz state that is typified by significant
expansion. The results of this expansion can be mold wall movement, Buckles,
scabs, Rat's tails etc...
Similarly Silica
sand having a relatively lower melting point compared to the other sands, has
issues with metals that approach and exceed 2240F in the form of
"Wetting" the point where metal starts to cover the surface of the
sand grain faces and Fluxes with Iron... (I don't really get the fluxing part,
but all will come clear in time...)
AFS Grain
Fineness Number (gfn) & Grain Distribution
Words like
"Fine, Medium & Coarse" are somewhat vague and subject to
interpretation in the abscence of some form of relativistic model... Thank God
the American Foundry Society stepped in and implemented a numeric scale that
does away with all that inaccuracy...
The AFS gfn covers
average grain size and distribution, as this is an average it may be somewhat
deceptive.
he AFS scale
typically covers 25 to 170 (according to the Text book) But I personally have
never heard of anything less than 80 or 90 on the coarse side and have regularly
heard of fine grains that top the 200 - 220 range...
And that's the
point!!! Don't confuse individual grain Mesh #'s with AFS gfn, as the gfn is an
AVERAGE!!!
Why such a
range??? Too coarse a gfn is reflected in the surface of the casting, too fine a
gfn and the mold can't pass the gases from the molten metal during the pour and
results in gas related defects.
And again on a
personal note, I know from painful experience if you can't pass gas, there will
be unpleasant results...
Sand
Handling
So if your sand is
a distribution of Mesh sizes that is averaged to an AFS gfn, then it would stand
to reason that you would want that distribution to stay, well, distributed...
Consider a tumbler
of sand rotating on an inclined axis, the fines grains move to the bottom, and
the coarse grains move to the top. Or just a conveyor that is dumping the sand
into a cone shaped pile, the fine grains typically will accumulate in the center
of the cone rising vertically as the cone builds surrounded by coarser material
rolling off to the sides and surrounding the base...
The above
illustrates examples of "Segregation" and will impact casting quality
if the AFS gfn distribution is not retained.
Sand
Reclamation
Man does this
Module never end...
So you have some
sand, you selected it based on the type that suits your casting specifications,
you ensured that you ordered the right AFS gfn for the metal or alloy to be
cast, You've employed 100's of 1,000's of dollars to ensure that the AFS gfn
distribution is retained, You cast you first casting and now what???
You open your
check book and hope that you can afford even more machinery to handle the task
of Sand Reclamation!!!
On the most basic
level the spent molds have to be broken up to make the sands flow for molding in
the next casting. Along with breaking-up the spent mold, "Sand Fines"
(sub-AFS gfn sized material that results from mechanical handling of the sand),
spent binder material and any metallic refuse need to be removed.
And for high
production foundries the sand has to be cooled prior to re-use if the production
cycle is that rapid.
As I said, get
that check book out as it ain't gonna be cheap...
Mechanical
Reclamation Processes
The following are
examples of various methods of mechanically reclaiming spent mold sands.
Jaw Crusher
Pneumatic
Scrubbers
Vibratory
Reduction
Shot Blast
Reduction
Mechanical Sand
Scrubber
Heating Units to
burn out residual binders - this is employed when dealing with chemically bonded
sands that use a resin that has cured and can not be re-activated... Excessive
amounts of cured resins that accumulate in the sand impact the LOI or Loss on
Ignition rating of the sand.
Sand Coolers
All of the above
should not aggravate the accumulation of "Fines" by excessively rough
handling of sands. Sands that are classed as angular impart specific properties
to the mold and casting, but those attributes are altered if the sand is literally
broken by force during the reclamation process and result in a sand that is now
round.
The removal of
metal(s) from the sand is also important as it will directly impact the
refractoriness of the sand and casting quality and defects. Especially in a
Jobber Foundry where various alloys are cast using the same sand if it suits the
purpose.